

It’s most useful for something like /home so you have a full backup of your home directories without having to worry if some app has dumped its settings on a folder you don’t have marked for backup. But also backing up / is useful because it gives you an easy recovery in the event of say disk failure. Just restore the entire system from a backup.
S-Mode is an appliance mode for Windows that prevents installation of any app not from the Microsoft Store. Disable S-Mode and you can install any application like you’ve always done, including Firefox.